7z in Centos 6.2 64bit
Add RPMForge repository
wget http://packages.sw.be/rpmforge-release/rpmforge-release-0.5.2-2.el6.rf.x86_64.rpm rpm -ivh rpmforge-release-0.5.2-2.el6.rf.x86_64.rpm
Install 7z
yum install p7zip
Extract file
7za x [7zfilename]
Compress file
7za a -mx=9 7zfilename.7z [filename/directory]